How do temperature changes affect solubility in general?

Prepare for the NCEA Level 3 Chemistry – Aqueous Chemistry (AS91393) Exam. Utilize flashcards and multiple choice questions with hints and explanations. Excel on your exam!

Temperature changes can significantly influence the solubility of substances, and the effect largely depends on the nature of the dissolution process involved. For many solid solutes in liquid solvents, an increase in temperature typically leads to an increase in solubility. This is due to the increased kinetic energy of the particles, which helps to overcome the attractive forces between solute particles and allows them to disperse more readily in the solvent.

Conversely, for some exothermic dissolution processes, where heat is released when a solute dissolves, an increase in temperature could lead to a decrease in solubility. In this case, the system shifts to counteract the temperature increase according to Le Chatelier's principle, thereby reducing the solubility of the solute.

For gaseous solutes, the effect of temperature on solubility is generally negative—higher temperatures tend to decrease the solubility of gases in liquids. This is because increased kinetic energy results in gas molecules being more likely to escape from the solvent into the atmosphere.

Thus, temperature changes can either increase or decrease solubility, making it correct to say that the impact depends on the type of reaction involved, reaffirming that this choice captures the essence of the relation between temperature and sol

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